Polypeptide Antibiotics

Overview

Polypeptide antibiotics are a class of antimicrobial agents composed of amino acid chains that exert their bactericidal activity through various mechanisms, primarily targeting the bacterial cell membrane.

Cyclic Peptide Antibiotics

Bacitracin

  • Classification: Cyclic peptide antibiotic
  • Mechanism of Action: Interferes with dephosphorylation in the bacterial cell wall synthesis pathway
  • Spectrum: Primarily active against Gram-positive bacteria
  • Clinical Use:
    • Topical applications (skin infections)
    • Limited systemic use due to nephrotoxicity
  • Adverse Effects: Nephrotoxicity when used systemically

Cycloserine

  • Classification: Cyclic peptide antibiotic
  • Mechanism of Action: Inhibits bacterial cell wall synthesis by blocking enzymes involved in peptidoglycan formation
  • Spectrum: Active against Mycobacterium tuberculosis
  • Clinical Use: Second-line treatment for tuberculosis
  • Adverse Effects:
    • CNS toxicity (seizures, psychosis)
    • Peripheral neuropathy

Mechanism Summary

Polypeptide antibiotics typically work by:

  1. Disrupting cell membrane integrity causing cell leakage
  2. Inhibiting cell wall synthesis enzymes
  3. Interfering with essential bacterial metabolic processes

Clinical Considerations

  • Narrow therapeutic index requires careful monitoring
  • Significant toxicity limits systemic use
  • Primarily topical applications for most polypeptide antibiotics
  • Resistance development is relatively uncommon but can occur